Justin Timberlake and Jessica Biel
Things started off rough for this couple when Biel was verbally assaulted by his ex, Cameron Diaz and when Timberlake was asked about the love of his life and responded "I haven't met her yet," early in their relationship. Biel was banned from touring with the singer but as the years passed, rumors of marriage seem more and more plausible. That is, until they split up in March of 2011.
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